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  Towards quantum mechanical description of the unconventional mass-dependent isotope effect in ozone: Resonance recombination in the strong collision approximation

Grebenshchikov, S. Y., & Schinke, R. (2009). Towards quantum mechanical description of the unconventional mass-dependent isotope effect in ozone: Resonance recombination in the strong collision approximation. Journal of Chemical Physics, 131, 181103-1-181103-4. doi:10.1063/1.3253994.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0029-12A7-3 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0029-12A8-1
Genre: Journal Article

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 Creators:
Grebenshchikov, Sergej Yuri1, Author
Schinke, Reinhard2, Author           
Affiliations:
1Max Planck Society, ou_persistent13              
2Max Planck Institute for Dynamics and Self-Organization, Max Planck Society, ou_2063285              

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 Abstract: The dependence of ozone recombination rate on the masses of oxygen isotopes is examined in the strong collision approximation by means of quantum mechanical calculations of resonance spectra of several rotating isotopomers. The measured ∆ ZPE effect and its temperature dependence can be reconstructed from partial widths of narrow nonoverlapping resonances. The effect is attributed to substantial contributions of highly rotationally excited states to recombination.

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Language(s): eng - English
 Dates: 2009-11-10
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 444413
DOI: 10.1063/1.3253994
 Degree: -

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Title: Journal of Chemical Physics
  Alternative Title : J. Chem. Phys.
Source Genre: Journal
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Pages: - Volume / Issue: 131 Sequence Number: - Start / End Page: 181103-1 - 181103-4 Identifier: -