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  Anisotropic Random Networks of Semiflexible Polymers

Benetatos, P., & Zippelius, A. (2007). Anisotropic Random Networks of Semiflexible Polymers. Physical Review Letters, 99: 198301. doi:10.1103/PhysRevLett.99.198301.

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 Urheber:
Benetatos, Panayotis, Autor
Zippelius, Annette1, Autor           
Affiliations:
1Fellow Group Polymers, complex fluids and disordered systems, Max Planck Institute for Dynamics and Self-Organization, Max Planck Society, ou_2063298              

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 Zusammenfassung: Motivated by the organization of cross-linked cytoskeletal biopolymers, we present a semimicroscopic replica field theory for the formation of anisotropic random networks of semiflexible polymers. The networks are formed by introducing random permanent cross-links which fix the orientations of the corresponding polymer segments to align with one another. Upon increasing the cross-link density, we obtain a continuous gelation transition from a fluid phase to a gel where a finite fraction of the system gets localized at random positions. For sufficiently stiff polymers, this positional localization is accompanied by a continuous isotropic-to-nematic (IN) transition occurring at the same cross-link density. As the polymer stiffness decreases, the IN transition becomes first order, shifts to a higher cross-link density, and is preceded by an amorphous solid where the average polymer orientations freeze in random directions.

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Sprache(n): eng - English
 Datum: 2007-11-09
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: eDoc: 346940
DOI: 10.1103/PhysRevLett.99.198301
 Art des Abschluß: -

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Titel: Physical Review Letters
  Alternativer Titel : Phys. Rev. Lett.
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: -
Seiten: - Band / Heft: 99 Artikelnummer: 198301 Start- / Endseite: - Identifikator: -