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  Hydrogen bonding in liquid water probed by resonant Auger-electron spectroscopy

Winter, B., Hergenhahn, U., Faubel, M., Björneholm, O., & Hertel, I. V. (2007). Hydrogen bonding in liquid water probed by resonant Auger-electron spectroscopy. Journal of Chemical Physics, 127(9): 094501. Retrieved from 10.1063/1.2770457.

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 Urheber:
Winter, B., Autor
Hergenhahn, U., Autor
Faubel, M.1, Autor           
Björneholm, O., Autor
Hertel, I. V., Autor
Affiliations:
1Group Spectroscopy of aqueous surfaces, Department of Dynamics of Complex Fluids, Max Planck Institute for Dynamics and Self-Organization, Max Planck Society, ou_2063314              

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 Zusammenfassung: We have measured resonant and off-resonant Auger-electron spectra of liquid water. Continuumlike transitions near and above the O1s vertical ionization energy are identified by the characteristic normal Auger-electron spectra. On the contrary, well-resolved spectator shifts of the main Auger-electron peak are observed at the liquid-water O1s absorption main edge and near the absorption pre-edge. The shifts of 1.4 and 1.9 eV arise from the localized nature of the excitation. Excited-state localization/delocalization is also discussed for the analogous vacuum ultraviolet (VUV) transitions, and we point out the similarities between x-ray and VUV absorption spectra of liquid water.

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Sprache(n): eng - English
 Datum: 2007-09-04
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: eDoc: 341621
URI: 10.1063/1.2770457
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Titel: Journal of Chemical Physics
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: -
Seiten: 6 Band / Heft: 127 (9) Artikelnummer: 094501 Start- / Endseite: - Identifikator: -