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  New theoretical investigations of the photodissociation of ozone in the Hartley, Huggins, Chappuis, and Wulf bands

Grebenshchikov, S. Y., Qu, Z.-W., Zhu, H., & Schinke, R. (2007). New theoretical investigations of the photodissociation of ozone in the Hartley, Huggins, Chappuis, and Wulf bands. Physical Chemistry Chemical Physics, 9, 2044-2064. doi:10.1039/b701020f.

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 Creators:
Grebenshchikov, Sergej Yuri1, Author
Qu, Zheng-Wang2, Author              
Zhu, Hui, Author
Schinke, Reinhard2, Author              
Affiliations:
1Max Planck Society, ou_persistent13              
2Max Planck Institute for Dynamics and Self-Organization, Max Planck Society, ou_2063285              

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 Abstract: We review recent theoretical studies of the photodissociation of ozone in the wavelength region from 200 nm to 1100 nm comprising four major absorption bands: Hartley and Huggins (near ultraviolet), Chappuis (visible), and Wulf (near infrared). The quantum mechanical dynamics calculations use global potential energy surfaces obtained from new high-level electronic structure calculations. Altogether nine electronic states are taken into account in the theoretical descriptions: four 1A', two 1A'', one 3A' and two 3A'' states. Of particular interest is the analysis of diffuse vibrational structures, which are prominent in all absorption bands, and their dynamical origin and assignment. Another focus is the effect of non-adiabatic coupling on lifetimes in the excited states and on the population of the specific electronic product channels.

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Language(s): eng - English
 Dates: 2007-03-15
 Publication Status: Published in print
 Pages: -
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 350942
DOI: 10.1039/b701020f
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Title: Physical Chemistry Chemical Physics
  Alternative Title : Phys. Chem. Chem. Phys.
Source Genre: Journal
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Pages: - Volume / Issue: 9 Sequence Number: - Start / End Page: 2044 - 2064 Identifier: -