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Zusammenfassung:
Many-body perturbation theory (MBPT) opens the possibility to construct approximations to every desired order of a ’weak’ interacting system. The drawback is a in general non-local interaction in space and time and it is therefore a demanding task to apply it to ’real’ systems.
The optimized effective potential (OEP), derived by inversion of the Sham-Schlüter equation, is a natural connection between local density-functional theory and MBPT. In principle, this variationally best local potential reduces the problem to solving a simple system of Kohn-Sham equations combined with the solution of the OEP integral equation. However, converging the full set of OEP equations is a quite challenging procedure and is in practice rarely tackled.
The Krieger-Li-Iafrate (KLI) approximation reduces the integral equation to an analytically solvable one via a dominant orbital approximation. It performs usually quite well for electronic systems.
In the present work, we extend the OEP and KLI approaches to the case of electron-photon interactions in quantum optics and
quantum electrodynamics. Here an effective electronic interaction is transmitted via transversal photons. We present first static
and time-dependent results for the OEP and KLI approximations of the Rabi model and compare with the exact configuration interaction solution and the corresponding exact Kohn-Sham potentials.
