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  Acid-Catalyzed Dehydration of Fructose to 5-(Hydroxymethyl)furfural

Qiao, Y., Theyssen, N., & Hou, Z. (2015). Acid-Catalyzed Dehydration of Fructose to 5-(Hydroxymethyl)furfural. Recyclable Catalysis, 2(1), 36-60. doi:10.1515/recat-2015-0006.

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 Creators:
Qiao, Yunxiang1, Author              
Theyssen, Nils1, Author              
Hou, Zhenshan1, 2, Author              
Affiliations:
1Service Department Theyssen (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445632              
2Key Laboratory for Advanced Material, Research Institute of Industrial Catalysis, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237 (P. R. China), ou_persistent22              

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Free keywords: Dehydration; Fructose; 5-(hydroxymethyl) furfural; Acid Catalysis; Recycling
 Abstract: Hydroxymethylfurfural (abbreviated as HMF), also 5-(hydroxymethyl)furfural, is an organic compound derived from dehydration of certain sugars. HMF is primarily considered as a starting material for liquid transportation fuels and polyester building block chemicals. The most convenient synthetic method of HMF is based on acidcatalyzed triple dehydration of fructose. Although there are many studies about fructose dehydration to 5-HMF since this field started to be investigated, it is necessary to provide a new review about fructose dehydration to 5-HMF. In the following, we will make a summary (in detail) of catalytic systems of fructose dehydration to HMF achieved by different acid catalysts, including mineral and organic acids, metal complexes, heteropoly acid-based materials, Ionic Liquids, ion-exchange resins, zeolites, functionalized carbonaceous materials and mesoporous silica materials. It has been demonstrated that nearly full conversion of fructose and 100% HMF selectivity could be obtained with some acidic catalytic systems up to now.

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Language(s): eng - English
 Dates: 2015-05-29
 Publication Status: Published online
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1515/recat-2015-0006
 Degree: -

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Title: Recyclable Catalysis
Source Genre: Journal
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Publ. Info: Warsaw, Poland : De Gruyter Open
Pages: - Volume / Issue: 2 (1) Sequence Number: - Start / End Page: 36 - 60 Identifier: ISSN: 2300-3561