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  Temperature and pressure dependence of the reaction S plus CS ( plus M) -> CS2 (+M).

Glarborg, P., Marshall, P., & Troe, J. (2015). Temperature and pressure dependence of the reaction S plus CS ( plus M) -> CS2 (+M). Journal of Physical Chemistry A, 119(28), 7277-7281. doi:10.1021/jp5121492.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0028-3766-4 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002A-2A84-1
Genre: Journal Article

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2181648.pdf (Publisher version), 306KB
 
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http://pubs.acs.org/doi/pdf/10.1021/jp5121492 (Publisher version)
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 Creators:
Glarborg, P., Author
Marshall, P., Author
Troe, J.1, Author              
Affiliations:
1Emeritus Group of Spectroscopy and Photochemical Kinetics, MPI for Biophysical Chemistry, Max Planck Society, ou_578625              

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 Abstract: Experimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) -> CS2 (+M) over wide temperature and pressure ranges. The results constitute an important input for the kinetic modeling of CS2 oxidation. CS2 dissociation proceeds as a spin-forbidden process whose detailed properties are still not well understood. The role of the singlet triplet transition involved is discussed.

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Language(s): eng - English
 Dates: 2015-01-272015-07-16
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1021/jp5121492
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Title: Journal of Physical Chemistry A
Source Genre: Journal
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Pages: - Volume / Issue: 119 (28) Sequence Number: - Start / End Page: 7277 - 7281 Identifier: -