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  Dynamic behaviour of monohaptoallylpalladium species: internal coordination as a driving force in allylic alkylation chemistry

Xie, L.-G., Bagutski, V., Audisio, D., Wolf, L. M., Schmidts, V., Hofmann, K., et al. (2015). Dynamic behaviour of monohaptoallylpalladium species: internal coordination as a driving force in allylic alkylation chemistry. Chemical Science, 6(10), 5734-5739. doi:10.1039/C5SC01867F.

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 Creators:
Xie, Lan-Gui1, Author
Bagutski, Viktor2, Author
Audisio, Davide3, Author              
Wolf, Larry M.4, Author              
Schmidts, Volker2, Author
Hofmann, Kathrin5, Author
Wirtz, Cornelia6, Author              
Thiel, Walter4, Author              
Thiele, Christina M.2, Author
Maulide, Nuno1, Author              
Affiliations:
1University of Vienna, Institute of Organic Chemistry, Währinger Strasse 38, 1090 Vienna, Austria , ou_persistent22              
2Technische Universität Darmstadt, Clemens Schöpf Institut für Organische Chemie und Biochemie, Alarich-Weiss-Str. 4, 64287 Darmstadt, Germany , ou_persistent22              
3Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445614              
4Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445590              
5Technische Universität Darmstadt, Eduard-Zintl-Institute, Alarich-Weiss-Str. 12, 64287 Darmstadt, Germany , ou_persistent22              
6Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445623              

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 Abstract: Contemporary catalytic procedures involving alkylpalladium(II) have enriched the arsenal of synthetic organic chemistry. Those transformations usually rely on internal coordination through “directing groups”, carefully designed to maximize catalytic efficiency and regioselectivity. Herein, we report structural and reactivity studies of a series of internally coordinated monohaptoallylpalladium complexes. These species enable the direct spectroscopic observation and theoretical study of π–σ–π interconversion processes. They further display unusual dynamic behavior which should be of direct relevance to chemistries beyond catalytic allylic alkylation.

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Language(s): eng - English
 Dates: 2015-05-232015-07-032015-07-062015-10-01
 Publication Status: Published in print
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C5SC01867F
 Degree: -

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Title: Chemical Science
  Other : Chem. Sci.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 6 (10) Sequence Number: - Start / End Page: 5734 - 5739 Identifier: ISSN: 2041-6520
CoNE: https://pure.mpg.de/cone/journals/resource/2041-6520