English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Ca3[BN2]I3: The First Halide-Rich Alkaline Earth Nitridoborate with Isolated [BN2]3- Units

Toros, T. E., Yahyaoglu, M., Aydemir, U., Drathen, C., Akselrud, L., Prots, Y., et al. (2015). Ca3[BN2]I3: The First Halide-Rich Alkaline Earth Nitridoborate with Isolated [BN2]3- Units. Zeitschrift für anorganische und allgemeine Chemie, 641(11), 2014-2019. doi:10.1002/zaac.201500285.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0028-F0B9-7 Version Permalink: http://hdl.handle.net/21.11116/0000-0001-17E3-5
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Toros, Turna Ezgi1, Author
Yahyaoglu, Mujde1, Author
Aydemir, Umut1, Author
Drathen, Christina1, Author
Akselrud, Lev, Author
Prots, Yurii2, Author              
Höhn, Peter3, Author              
Somer, Mehmet1, Author
Affiliations:
1External Organizations, ou_persistent22              
2Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863424              
3Peter Höhn, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863419              

Content

show
hide
Free keywords: -
 Abstract: The title compound Ca-3[BN2]I-3 was obtained from reactions of mixtures of the starting materials Ca-3[BN2](2) and CaI2 in a 1:4 ratio in sealed Nb tubes at 1223 K. The crystal structure was solved from powder synchrotron diffraction data. Ca-3[BN2]I-3 is the first example of a halide-rich nitridoborate crystallizing in the rhombohedral space group R32 [no. 155, Pearson code: hR96; Z = 12; a = 16.70491(2) angstrom, c = 12.41024(2) angstrom]. The crystal structure is built up by two interpenetrating networks of condensed edge-sharing [BN2]@Ca-6 and [square]@I-6 trigonal antiprisms (square = void). In Ca-3[BN2]I-3 two crystallograhically distinct [BN2](3-) anions are present with d(B1-N) = 1.393(2) angstrom and d(B2-N) = 1.369(9) angstrom. Their bond angles are practically linear, varying only slightly: N-B1-N = 179(1)degrees and N-B2-N = 180 degrees. Vibrational spectra were interpreted based on the D-infinity h symmetry of the discrete linear [N-B-N](3-) moieties, considering the site symmetry reduction and the presence of two distinct [BN2](3-) groups.

Details

show
hide
Language(s): eng - English
 Dates: 2015-08-14
 Publication Status: Published online
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000362691000028
DOI: 10.1002/zaac.201500285
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 641 (11) Sequence Number: - Start / End Page: 2014 - 2019 Identifier: ISSN: 0044-2313
CoNE: /journals/resource/954925453895