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  Elucidating Charge Delocalization in the High-Spin State of aqueous FeII Spin-Crossover Compounds via Time-Resolved Spectroscopy in the X-ray Water Window

Huse, N., Van Kuiken, B. E., Cho, H., Strader, M. L., Kim, T. K., Khalil, M., et al. (2013). Elucidating Charge Delocalization in the High-Spin State of aqueous FeII Spin-Crossover Compounds via Time-Resolved Spectroscopy in the X-ray Water Window. EPJ Web of Conferences, 41: 05037. doi:10.1051/epjconf/20134105037.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0029-1A1A-7 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0029-1A1B-5
Genre: Conference Paper

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epjconf_up2012_05037.pdf (Publisher version), 738KB
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epjconf_up2012_05037.pdf
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Copyright Date:
2013
Copyright Info:
© Owned by the authors, published by EDP Sciences

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Locator:
http://dx.doi.org/10.1051/epjconf/20134105037 (Publisher version)
Description:
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Creators

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 Creators:
Huse, Nils1, 2, 3, Author              
Van Kuiken, Benjamin E.4, Author
Cho, Hana3, 5, Author
Strader, Matthew L.3, Author
Kim, Tae Kyu5, Author
Khalil, Munira4, Author
Schoenlein, Robert W.3, Author
Affiliations:
1Ultrafast Molecular Dynamics, Research Groups, Max Planck Research Department for Structural Dynamics, Department of Physics, University of Hamburg, External Organizations, ou_2173640              
2Center for Free Electron Laser Science, 22607 Hamburg, Germany , ou_persistent22              
3Ultrafast X-ray Science Lab, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA, ou_persistent22              
4Department of Chemistry, University of Washington, Seattle, Washington 98195, USA , ou_persistent22              
5Department of Chemistry, Pusan National University, Geumjeong-gu, Busan 609-735, Korea, ou_persistent22              

Content

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Free keywords: Chemistry – Condensed Phase
 Abstract: We report the first time-resolved spectroscopy of aqueous solution in the Xray water window. Nitrogen K-edge spectra, combined with ab initio calculations, reveal distinct charge delocalization, shedding light on the origins of ultrafast spin crossover.

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Language(s): eng - English
 Dates: 2013-03-13
 Publication Status: Published online
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Method: Internal
 Identifiers: DOI: 10.1051/epjconf/20134105037
 Degree: -

Event

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Title: XVIIIth International Conference on Ultrafast Phenomena
Place of Event: Lausanne, Switzerland
Start-/End Date: 2013-07-08 - 2013-07-13

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Source 1

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Title: EPJ Web of Conferences
  Other : XVIIIth International Conference on Ultrafast Phenomena
Source Genre: Journal
 Creator(s):
Chergui, M. , Editor
Taylor, A. , Editor
Cundiff, S. , Editor
de Vivie-Riedle, R. , Editor
Yamagouchi, K. , Editor
Affiliations:
-
Publ. Info: Les Ulis : EDP Sciences
Pages: - Volume / Issue: 41 Sequence Number: 05037 Start / End Page: - Identifier: CoNE: /journals/resource/2100-014X
ISBN: 978-2-7598-0956-1