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  Nitrogen Backbone Oligomers

Wang, H., Eremets, M. I., Troyan, I., Liu, H., Ma, Y., & Vereecken, L. (2015). Nitrogen Backbone Oligomers. Scientific Reports, 5: 13239. doi:10.1038/srep13239.

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 Creators:
Wang, Hongbo1, Author           
Eremets, Mikhail I.1, Author           
Troyan, Ivan1, Author           
Liu, Hanyu2, Author
Ma, Yanming2, Author
Vereecken, Luc3, Author           
Affiliations:
1Biogeochemistry, Max Planck Institute for Chemistry, Max Planck Society, ou_1826286              
2external, ou_persistent22              
3Atmospheric Chemistry, Max Planck Institute for Chemistry, Max Planck Society, ou_1826285              

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 Abstract: We found that nitrogen and hydrogen directly react at room temperature and pressures of similar to 35 GPa forming chains of single-bonded nitrogen atom with the rest of the bonds terminated with hydrogen atoms - as identified by IR absorption, Raman, X-ray diffraction experiments and theoretical calculations. At releasing pressures below similar to 10 GPa, the product transforms into hydrazine. Our findings might open a way for the practical synthesis of these extremely high energetic materials as the formation of nitrogen-hydrogen compounds is favorable already at pressures above 2 GPa according to the calculations.

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 Dates: 2015
 Publication Status: Published online
 Pages: -
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 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: 000359719300001
DOI: 10.1038/srep13239
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Title: Scientific Reports
  Abbreviation : Sci. Rep.
Source Genre: Journal
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Publ. Info: London, UK : Nature Publishing Group
Pages: - Volume / Issue: 5 Sequence Number: 13239 Start / End Page: - Identifier: Other: 2045-2322
CoNE: https://pure.mpg.de/cone/journals/resource/2045-2322