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  Pseudomorphic Generation of Supported Catalysts for Glycerol Oxidation

Deng, X., Dodekatos, G., Pupovac, K., Weidenthaler, C., Schmidt, W., Schüth, F., et al. (2015). Pseudomorphic Generation of Supported Catalysts for Glycerol Oxidation. ChemCatChem, 7(23), 3832-3837. doi:10.1002/cctc.201500703.

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 Creators:
Deng, Xiaohui1, Author              
Dodekatos, Georgios1, Author              
Pupovac, Kristina2, Author              
Weidenthaler, Claudia3, Author              
Schmidt, Wolfgang4, Author              
Schüth, Ferdi5, Author              
Tüysüz, Harun1, Author              
Affiliations:
1Research Group Tüysüz, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1950290              
2Research Group Palkovits, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445615              
3Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1950291              
4Research Group Schmidt, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445618              
5Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              

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Free keywords: alcohol reduction; copper; nanoparticles; mesoporous materials; oxidation
 Abstract: A catalyst consisting of copper nanoparticles (15–20 nm in size) supported on ordered mesoporous cobalt monoxide was synthesized by the one-step reduction of ethanol from nanocast copper cobalt spinel oxides. The small-angle X-ray scattering patterns showed that the ordered mesostructure was maintained after post-treatment, and the cross-section scanning electron microscopy images showed that the Cu nanoparticles were distributed homogeneously throughout the mesoporous CoO framework. The materials were tested as noble-metal-free catalysts for the oxidation of glycerol under alkaline conditions. The catalytic data showed that the presence of Cu nanoparticles greatly enhanced the catalytic performance.

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Language(s): eng - English
 Dates: 2015-06-182015-10-192015-12-01
 Publication Status: Published online
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/cctc.201500703
 Degree: -

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Title: ChemCatChem
  Other : ChemCatChem
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 7 (23) Sequence Number: - Start / End Page: 3832 - 3837 Identifier: ISSN: 1867-3880
CoNE: https://pure.mpg.de/cone/journals/resource/1867-3880