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  The use of a combination of RDC and chiroptical spectroscopy for determination of the absolute configuration of fusariumin A from the fungus Fusarium sp.

Liu, L. Y., Sun, H., Griesinger, C., & Liu, J. K. (2016). The use of a combination of RDC and chiroptical spectroscopy for determination of the absolute configuration of fusariumin A from the fungus Fusarium sp. Natural Products and Bioprospecting, 6(1), 41-48. doi:10.1007/s13659-015-0084-0.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0029-6AA9-6 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-DFC5-A
Genre: Journal Article

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 Creators:
Liu, L. Y., Author
Sun, H.1, Author              
Griesinger, C.1, Author              
Liu, J. K., Author
Affiliations:
1Department of NMR Based Structural Biology, MPI for biophysical chemistry, Max Planck Society, ou_578567              

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Free keywords: NMR; Residual dipolar coupling; Relative configuration; Absolute configuration; Chiroptics
 Abstract: A new alkylpyrrole derivative, fusariumin A (1), was isolated from the culture broth of the fungus Fusarium sp. The absolute configuration of fuasiumin A has been established as (2'R,3'R) using a combination of RDC (residual dipolar coupling)-based NMR and DFT-supported chiroptical spectroscopy. It is worth to note that in this study without the aid of the RDC analysis, an unambiguous determination of configuration and conformation was not feasible due to the excessive conformational possibilities of this open-chain compound.

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Language(s): eng - English
 Dates: 2016-01-20
 Publication Status: Published online
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 Rev. Method: Peer
 Identifiers: DOI: 10.1007/s13659-015-0084-0
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Title: Natural Products and Bioprospecting
Source Genre: Journal
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Pages: - Volume / Issue: 6 (1) Sequence Number: - Start / End Page: 41 - 48 Identifier: -