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  An element through the looking glass: exploring the Au–C, Au–H and Au–O energy landscape

Roşca, D.-A., Wright, J. A., & Bochmann, M. (2015). An element through the looking glass: exploring the Au–C, Au–H and Au–O energy landscape. Dalton Transactions, 44(48), 20785-20807. doi:10.1039/C5DT03930D.

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 Creators:
Roşca, Dragoş-Adrian1, 2, Author              
Wright, Joseph A.2, Author
Bochmann, Manfred2, Author
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2School of Chemistry, University of East Anglia, Norwich, UK, ou_persistent22              

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 Abstract: Gold, the archetypal “noble metal”, used to be considered of little interest in catalysis. It is now clear that this was a misconception, and a multitude of gold-catalysed transformations has been reported. However, one consequence of the long-held view of gold as inert metal is that its organometallic chemistry contains many “unknowns”, and catalytic cycles devised to explain gold's reactivity draw largely on analogies with other transition metals. How realistic are such mechanistic assumptions? In the last few years a number of key compound classes have been discovered that can provide some answers. This Perspective attempts to summarise these developments, with particular emphasis on recently discovered gold(III) complexes with bonds to hydrogen, oxygen, alkenes and CO ligands.

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Language(s): eng - English
 Dates: 2015-10-072015-11-122015-11-132015-12-28
 Publication Status: Published in print
 Pages: 23
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C5DT03930D
 Degree: -

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Title: Dalton Transactions
  Other : Dalton Trans.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 44 (48) Sequence Number: - Start / End Page: 20785 - 20807 Identifier: ISSN: 1477-9226
CoNE: https://pure.mpg.de/cone/journals/resource/954925269323