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Schlagwörter:
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Zusammenfassung:
The polarization transfer dynamics in a recently introduced deuterium-carbon NMR correlation method is studied, both theoretically and experimentally. The technique, which exploits heteronuclear multiple−quantum coherences, is useful for measuring and assigning 2H quadrupolar couplings in ordered media. It is also shown that the experiment is suitable for implementation under off−magic−angle spinning conditions. The approach is demonstrated on a perdeuterated liquid crystal