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  Bad-Metal-Layered Sulfide Oxide CsV2S2O

Valldor, M., Merz, P., Prots, Y., & Schnelle, W. (2016). Bad-Metal-Layered Sulfide Oxide CsV2S2O. European Journal of Inorganic Chemistry, (1), 23-27. doi:10.1002/ejic.201501154.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0029-7DE9-6 Version Permalink: http://hdl.handle.net/21.11116/0000-0001-0027-3
Genre: Journal Article

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 Creators:
Valldor, Martin1, Author              
Merz, Patrick2, Author              
Prots, Yurii3, Author              
Schnelle, Walter4, Author              
Affiliations:
1Martin Valldor, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863454              
2Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              
3Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863424              
4Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863441              

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 Abstract: Through a solid-state reaction between stoichiometric amounts of a mixed cesium oxide Cs2O1.3, VS, S, and V2O5, a polycrystalline powder of CsV2S2O was obtained. Small single crystals could be grown in a CsCl melt by allowing Cs2SO4, V metal and S powders to react. The crystals have a plate-like morphology, consistent with the tetragonal crystal-structure symmetry [P4/mmm, a = 3.9455(1), c = 7.4785(1) angstrom]. Magnetic measurements suggest that CsV2S2O is a temperature-independent paramagnet, and resistivity data concur with a bad metal. The mixed oxidation state of V on one crystallographic site offers a tentative explanation of the electronic properties of the title compound.

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Language(s): eng - English
 Dates: 2016-01-182016-01-18
 Publication Status: Published in print
 Pages: -
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 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000367727600004
DOI: 10.1002/ejic.201501154
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Title: European Journal of Inorganic Chemistry
  Other : Eur. J. Inorg. Chem.
Source Genre: Journal
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Publ. Info: Weinheim, Germany : Wiley-VCH
Pages: - Volume / Issue: (1) Sequence Number: - Start / End Page: 23 - 27 Identifier: ISSN: 1434-1948
CoNE: /journals/resource/954926953810_1