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  Chemical bonding in MgAgAs-type compounds

Bende, D., Grin, Y., & Wagner, F. R. (2016). Chemical bonding in MgAgAs-type compounds. In C. Felser (Ed.), Heusler Alloys (pp. 133-156). Cham: Springer.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0029-B2CD-B Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0029-B2CE-9
Genre: Book Chapter

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 Creators:
Bende, D.1, Author           
Grin, Yu.2, Author           
Wagner, F. R.3, Author           
Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
2Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413              
3Frank Wagner, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863409              

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 Abstract: The chemical bonding in MgAgAs-type compounds of the main-group elements is analyzed with the aid of quantum chemical direct-space techniques.These phases show a variety of different bonding patterns from highly covalent interactions as in diamond to mostly ionic bonding as in the zinc-blende type compound BeS. The formal concept of the 8− N rule (octet rule) is related to the direct-space techniques to rationalize the results and compare the MgAgAs-type compounds with classical valence compounds like elements of the diamond structure, zinc-blende and Zintl phases. © Springer International Publishing Switzerland 2016.

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Language(s): eng - English
 Dates: 2016-01-14
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1007/978-3-319-21449-8_6
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Title: Heusler Alloys
Source Genre: Book
 Creator(s):
Felser, Claudia1, Editor           
Affiliations:
1 Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863429            
Publ. Info: Cham : Springer
Pages: - Volume / Issue: - Sequence Number: - Start / End Page: 133 - 156 Identifier: ISBN: 978-3-319-21448-1

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Title: Springer Series in Materials Science
Source Genre: Series
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Pages: - Volume / Issue: 222 Sequence Number: - Start / End Page: - Identifier: -