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  Vibrational inelasticity of highly vibrationally excited NO on Ag(111).

Krüger, B. C., Meyer, S., Kandratsenka, A., Wodtke, A. M., & Schäfer, T. (2016). Vibrational inelasticity of highly vibrationally excited NO on Ag(111). The Journal of Physical Chemistry Letters, 7(3), 441-446. doi:10.1021/acs.jpclett.5b02448.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0029-C3FA-F Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-D10A-2
Genre: Journal Article

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2251127.pdf (Publisher version), 2MB
 
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 Creators:
Krüger, B. C., Author
Meyer, S., Author
Kandratsenka, A.1, Author              
Wodtke, A. M.1, Author              
Schäfer, T., Author
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1Department of Dynamics at Surfaces, MPI for Biophysical Chemistry, Max Planck Society, ou_578600              

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 Abstract: Multiquantum relaxation of highly vibrationally excited nitric oxide on noble metals has become one of the best studied examples of the Born-Oppenheimer approximation's failure to describe molecular interactions at metal surfaces. When first reported, relaxation of highly vibrationally excited NO occurring in collisions with Au(In) surfaces exhibited the largest vibrational inelasticity seen in molecule-surface collisions, and no system has been found to date exhibiting a greater vibrational inelasticity. In this work, we compare the relaxation of NO(v = 11) in scattering events on Ag(111) to that on Au(111). The relaxation probability and the average vibrational energy loss are much higher when scattering from Ag( HI). We discuss possible reasons for this remarkable phenomenon, which may be related to the dissociation of NO, possible on Ag(111) at lower energy compared with Au(111).

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Language(s): eng - English
 Dates: 2016-01-132016-02-04
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1021/acs.jpclett.5b02448
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Title: The Journal of Physical Chemistry Letters
Source Genre: Journal
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Pages: - Volume / Issue: 7 (3) Sequence Number: - Start / End Page: 441 - 446 Identifier: -