Help Privacy Policy Disclaimer
  Advanced SearchBrowse


  230Th/U-dating of carbonate deposits from ancient aqueducts

Wenz, S., Scholz, D., Suermelihindi, G., Passchier, C. W., Jochum, K. P., & Andreae, M. O. (2016). 230Th/U-dating of carbonate deposits from ancient aqueducts. Quaternary Geochronology, 32, 40-52. doi:10.1016/j.quageo.2015.12.001.

Item is


show Files




Wenz, Sarah1, Author
Scholz, Denis1, Author
Suermelihindi, Guel1, Author
Passchier, Cornelis W.1, Author
Jochum, Klaus P.2, Author              
Andreae, Meinrat O.3, Author              
1external, ou_persistent22              
2Climate Geochemistry, Max Planck Institute for Chemistry, Max Planck Society, ou_2237635              
3Biogeochemistry, Max Planck Institute for Chemistry, Max Planck Society, ou_1826286              


Free keywords: -
 Abstract: Carbonate deposits in aqueducts, known as calcareous sinter, can reach a considerable thickness and are commonly annually laminated. Environmental and palaeoclimate proxies measured in calcareous sinter samples, such as stable oxygen and carbon isotopes and trace elements, can provide important high resolution information on hydrological conditions, temperature, and local precipitation in the catchment area of an aqueduct. In order to utilize the proxy data for palaeoclimate reconstruction, the sinter deposits must be dated by annual laminae counting and more precisely by 230Th/U-dating. The major problem of 230Th/U-dating of calcareous sinter in aqueducts is the relatively large amount of initial detrital Th contained in the deposits, leading to apparently wrong 230Th/U-ages. Here we present the first systematic approach to date sinter deposits from various locations in western and eastern Europe using the 230Th/U-method. Calcareous sinter samples from eight Roman aqueducts in France, Germany, Greece, and Turkey were investigated. Preliminary screening for the U and Th content of the samples by LA-MC-ICPMS revealed that the 238U/232Th isotope ratio of the samples is highly variable, with values ranging from 0.03 to >11. The four samples with the largest 238U/232Th ratios were selected for MC-ICPMS 230Th/U-dating, even though they still contain substantial amounts of detrital 232Th. The uncorrected 230Th/U-ages are between 2.9 and 461 a and thus all significantly older than required by the Roman origin of the samples (ca. 2 ka). Application of the conventional correction for detrital contamination, assuming a bulk Earth 232Th/238U weight ratio of 3.8 (±50%) and 230Th, 234U, and 238U in secular equilibrium, results in younger ages that are in agreement within error with a Roman origin. However, the resulting errors are very large, and the ages are therefore not very reliable. Application of three-dimensional isochrons yields both younger ages and smaller age uncertainties than the conventional detrital correction. However, the isochron age uncertainties are still between 0.8 and 1 ka and thus not as precise as required for paleoclimate and archaeological studies. Precise and accurate 230TH/U-dating of these relatively young Roman sinter deposits is therefore challenging. The observed high MSWD values (Mean Square of Weighted Deviates) and low Probabilities of Fit of all isochrons show that the isochron assumptions are not fulfilled for our samples. However, it is possible to estimate the degree of scatter around the isochron produced by different processes and simulate the different scenarios in Monte-Carlo simulations. These simulations show that the scatter observed in our isochron data cannot be explained by different ages and initial (234U/238) activity ratios of different sub samples, but also requires variable (230Th/232Th) activity ratios of the detrital component. (C) 2015 Elsevier B.V. All rights reserved.


 Dates: 2016-04
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Degree: -



Legal Case


Project information


Source 1

Title: Quaternary Geochronology
Source Genre: Journal
Publ. Info: Elsevier
Pages: - Volume / Issue: 32 Sequence Number: - Start / End Page: 40 - 52 Identifier: ISSN: 1871-1014
CoNE: https://pure.mpg.de/cone/journals/resource/1000000000238470