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  Poly(1-vinyl-1,2,4-triazolium) poly(ionic liquid)s : synthesis and the unique behavior in loading metal ions

Zhang, W., & Yuan, J. (2016). Poly(1-vinyl-1,2,4-triazolium) poly(ionic liquid)s: synthesis and the unique behavior in loading metal ions. Macromolecular Rapid Communications, 37(14), 1124-1129. doi:10.1002/marc.201600001.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002A-236A-A Version Permalink: http://hdl.handle.net/21.11116/0000-0007-E6FC-A
Genre: Journal Article

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 Creators:
Zhang, Weiyi1, Author              
Yuan, Jiayin1, Author              
Affiliations:
1Jiayin Yuan, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863318              

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Free keywords: metal adsorption, poly(1-vinyl-1,2,4-triazolium), poly(ionic liquid)s
 Abstract: Herein, the synthesis of a series of poly(4-alkyl-1-vinyl-1,2,4-triazolium) poly(ionic liquid)s is reported either via straightforward free radical polymerization of their corresponding ionic liquid monomers or via anion metathesis of the polymer precursors bearing halide as counter anion. The ionic liquid monomers are first prepared via N-alkylation reaction of commercially available 1-vinyl-1,2,4-triazole with alkyl iodides, followed by anion metathesis with targeted fluorinated anions. The thermal properties and solubilities of these poly(ionic liquid)s have been systematically investigated. Interestingly, it is found that the poly(4-ethyl-1-vinyl-1,2,4-triazolium) poly(ionic liquid) exhibited an improved loading capacity of transition metal ions in comparison with its imidazolium counterpart.

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 Dates: 2016-03-142016
 Publication Status: Published in print
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 Identifiers: DOI: 10.1002/marc.201600001
arXiv: 1609.01215
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Title: Macromolecular Rapid Communications
Source Genre: Journal
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Publ. Info: Weinheim, Germany : Wiley-VCH
Pages: - Volume / Issue: 37 (14) Sequence Number: - Start / End Page: 1124 - 1129 Identifier: ISSN: 1022-1336