English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  The low-temperature 13C and 2H spectra and relaxation rates of methyl groups depend on the azimutz of B0 in the molecular frame. Those of 1H do not. Why?

Gutsche, P., & Haeberlen, U. (2004). The low-temperature 13C and 2H spectra and relaxation rates of methyl groups depend on the azimutz of B0 in the molecular frame. Those of 1H do not. Why? Solid State Nuclear Magnetic Resonance, 26(1), 46-50. doi:10.1016/j.ssnmr.2003.11.002.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002A-192B-3 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-002A-192C-1
Genre: Journal Article
Alternative Title : The low-temperature 13C and 2H spectra and relaxation rates of methyl groups depend on the azimutz of B0 in the molecular frame. Those of 1H do not. Why?

Files

show Files
hide Files
:
SolidStateNMR_26_2004_46.pdf (Any fulltext), 212KB
 
File Permalink:
-
Name:
SolidStateNMR_26_2004_46.pdf
Description:
-
OA-Status:
Visibility:
Restricted (Max Planck Institute for Medical Research, MHMF; )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Creators

show
hide
 Creators:
Gutsche, Peter1, Author           
Haeberlen, Ulrich1, Author           
Affiliations:
1Research Group Prof. Dr. Haeberlen, Max Planck Institute for Medical Research, Max Planck Society, ou_1497739              

Content

show
hide
Free keywords: Relaxation; Spectra; Symmetry; Permutation
 Abstract: It is shown that the answer to the question asked in the title is: Because the axial symmetry axes of the H-H dipolar coupling tensors in a -CH3 group are perpendicular to the (assumed) threefold axis of the group. By contrast, those of the 13C-H dipolar and 2H quadrupolar coupling tensors are not. The use of "symmetry adapted" spin functions and of a symmetry adapted form of the (dipolar) coupling Hamiltonian greatly simplifies the analysis.

Details

show
hide
Language(s): eng - English
 Dates: 2003-08-212004-01-062004-01-062004-08-01
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 665559
DOI: 10.1016/j.ssnmr.2003.11.002
URI: http://www.ncbi.nlm.nih.gov/pubmed/15157538
URI: http://www.sciencedirect.com/science/article/pii/S0926204003001310
Other: 6424
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Solid State Nuclear Magnetic Resonance
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: San Diego, CA : Academic Press
Pages: - Volume / Issue: 26 (1) Sequence Number: - Start / End Page: 46 - 50 Identifier: ISSN: 0926-2040
CoNE: https://pure.mpg.de/cone/journals/resource/954925567752