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  Amino acid-derived N-heterocyclic carbene palladium complexes for aqueous phase Suzuki-Miyaura couplings

Steeples, E., Kelling, A., Schilde, U., & Esposito, D. (2016). Amino acid-derived N-heterocyclic carbene palladium complexes for aqueous phase Suzuki-Miyaura couplings. New Journal of Chemistry, 40(6), 4922-4930. doi:10.1039/C5NJ03337C.

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Steeples, Elliot1, Author              
Kelling, Alexandra, Author
Schilde, Uwe, Author
Esposito, Davide1, Author              
Affiliations:
1Davide Esposito, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863315              

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Free keywords: Open Access
 Abstract: In this work, three ligands produced from amino acids were synthesized and used to produce five bis- and PEPPSI-type palladium-NHC complexes using a novel synthesis route from sustainable starting materials. Three of these complexes were used as precatalysts in the aqueous-phase Suzuki-Miyaura coupling of various substrates displaying high activity. TEM and mercury poisoning experiments provide evidence for Pd-nanoparticle formation stabilized in water.

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 Dates: 2016-03-292016
 Publication Status: Published in print
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 Identifiers: DOI: 10.1039/C5NJ03337C
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Title: New Journal of Chemistry
Source Genre: Journal
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Publ. Info: London : Royal Society of Chemistry
Pages: - Volume / Issue: 40 (6) Sequence Number: - Start / End Page: 4922 - 4930 Identifier: ISSN: 1144-0546