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  Catalytic Enantioselective Conversion of Epoxides to Thiiranes.

Liao, S., Leutzsch, M., Monaco, M. R., & List, B. (2016). Catalytic Enantioselective Conversion of Epoxides to Thiiranes. Journal of the American Chemical Society, 138(16), 5230-5233. doi:10.1021/jacs.6b01960.

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 Creators:
Liao, Saihu1, Author              
Leutzsch, Markus1, Author              
Monaco, Mattia Ricardo1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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 Abstract: A highly efficient and enantioselective Brønsted acid catalyzed conversion of epoxides to thiiranes has been developed. The reaction proceeds in a kinetic resolution, furnishing both epoxide and thiirane in high yields and enantiomeric purity. Heterodimer formation between the catalyst and sulfur donor affords an effective way to prevent catalyst decomposition and enables catalyst loadings as low as 0.01 mol %.

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Language(s): eng - English
 Dates: 2016-02-222016-04-122016-04-27
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/jacs.6b01960
 Degree: -

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Title: Journal of the American Chemical Society
  Other : JACS
  Abbreviation : J. Am. Chem. Soc.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 138 (16) Sequence Number: - Start / End Page: 5230 - 5233 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870