English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  β-Ag3RuO4, a Ruthenate(V) Featuring Spin Tetramers on a Two-Dimensional Trigonal Lattice

Prasad, B. E., Kazin, P., Komarek, A. C., Felser, C., & Jansen, M. (2016). β-Ag3RuO4, a Ruthenate(V) Featuring Spin Tetramers on a Two-Dimensional Trigonal Lattice. Angewandte Chemie International Edition in English, 55(14), 4467-4471. doi:10.1002/anie.201510576.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002A-4FD5-7 Version Permalink: http://hdl.handle.net/21.11116/0000-0001-668C-F
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Prasad, Beluvalli E.1, Author              
Kazin, Pavel2, Author              
Komarek, A. C.3, Author              
Felser, Claudia4, Author              
Jansen, Martin1, Author              
Affiliations:
1Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              
2Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
3Alexander Komarek, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863446              
4Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863429              

Content

show
hide
Free keywords: -
 Abstract: Open-shell solids exhibit a plethora of intriguing physical phenomena that arise from a complex interplay of charge, spin, orbital, and spin-state degrees of freedom. Comprehending these phenomena is an indispensable prerequisite for developing improved functional materials. This type of understanding can be achieved, on the one hand, by experimental and theoretical investigations into known systems, or by synthesizing new solids displaying unprecedented structural and/or electronic features. -Ag3RuO4 may serve as such a model system because it possesses a remarkable anionic structure, consisting of tetrameric polyoxoanions (Ru4O16)(12-), and is an embedded fragment of a 2D trigonal MO2 lattice. The notorious frustration of antiferromagnetic (AF) exchange couplings on such lattices is thus lifted, and instead strong AF occurs within the oligomeric anion, where only one exchange path remains frustrated among the relevant six. The strong magnetic anisotropy of the [Ru4O16](12-) ion, and the effectively orbital nature of its net magnetic moment, implies that this anion may reveal the properties of a single-molecule magnet if well-diluted in a diamagnetic matrix.

Details

show
hide
Language(s): eng - English
 Dates: 2016-03-042016-03-04
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000373133000007
DOI: 10.1002/anie.201510576
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Angewandte Chemie International Edition in English
  Other : Angewandte Chemie, International Edition in English
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 55 (14) Sequence Number: - Start / End Page: 4467 - 4471 Identifier: ISSN: 0570-0833
CoNE: /journals/resource/0570-0833