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  Charge transfer in dissociating iodomethane and fluoromethane molecules ionized by intense femtosecond X-ray pulses.

Boll, R., Erk, B., Coffee, R., Trippel, S., Kierspel, T., Bomme, C., et al. (2016). Charge transfer in dissociating iodomethane and fluoromethane molecules ionized by intense femtosecond X-ray pulses. Structural Dynamics, 3(4): 043207. doi:10.1063/1.4944344.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002A-50F1-3 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-8135-4
Genre: Journal Article

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 Creators:
Boll, R., Author
Erk, B., Author
Coffee, R., Author
Trippel, S., Author
Kierspel, T., Author
Bomme, C., Author
Bozek, J. D., Author
Burkett, M., Author
Carron, S., Author
Ferguson, K. R., Author
Foucar, L., Author
Küpper, J., Author
Marchenko, T., Author
Miron, C., Author
Patanen, M., Author
Osipov, T., Author
Schorb, S., Author
Simon, M., Author
Swiggers, M., Author
Techert, S.1, Author              
Ueda, K., AuthorBostedt, C., AuthorRolles, D., AuthorRudenko, A., Author more..
Affiliations:
1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for biophysical chemistry, Max Planck Society, ou_578564              

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 Abstract: Ultrafast electron transfer in dissociating iodomethane and fluoromethane molecules was studied at the Linac Coherent Light Source free-electron laser using an ultraviolet-pump, X-ray-probe scheme. The results for both molecules are discussed with respect to the nature of their UV excitation and different chemical properties. Signatures of long-distance intramolecular charge transfer are observed for both species, and a quantitative analysis of its distance dependence in iodomethane is carried out for charge states up to I(21+). The reconstructed critical distances for electron transfer are in good agreement with a classical over-the-barrier model and with an earlier experiment employing a near-infrared pump pulse.

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Language(s): eng - English
 Dates: 2016-07
 Publication Status: Published online
 Pages: -
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 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1063/1.4944344
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Title: Structural Dynamics
Source Genre: Journal
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Pages: 15 Volume / Issue: 3 (4) Sequence Number: 043207 Start / End Page: - Identifier: -