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  Electronically non-adiabatic influences in surface chemistry and dynamics.

Wodtke, A. M. (2016). Electronically non-adiabatic influences in surface chemistry and dynamics. Chemical Society Reviews, 45(13), 3641-3657. doi:10.1039/C6CS00078A.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002A-51EA-D Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-296A-2
Genre: Journal Article

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Wodtke, A. M.1, Author              
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1Department of Dynamics at Surfaces, MPI for biophysical chemistry, Max Planck Society, ou_578600              

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 Abstract: Electronically nonadiabatic interactions between molecules and metal surfaces are now well known. Evidence is particularly clear from studies of diatomic molecules that molecular vibration can be strongly coupled to electrons of the metal leading to efficient energy transfer between these two kinds of motion. Since molecular vibration is the same motion needed for bond breaking, it is logical to postulate that electronically nonadiabatic influences on surface chemical reaction probabilities would be strong. Still there are few if any examples where such influences have been clearly investigated. This review recounts the evidence for and against the aforementioned postulate emphasizing reacting systems that have yet to receive full attention and where electronically nonadiabatic influence of reaction probabilities might be clearly demonstrated.

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Language(s): eng - English
 Dates: 2016-05-062016-07-07
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1039/C6CS00078A
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Title: Chemical Society Reviews
Source Genre: Journal
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Pages: - Volume / Issue: 45 (13) Sequence Number: - Start / End Page: 3641 - 3657 Identifier: -