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  Perspective: The first ten years of broadband chirped pulse Fourier transform microwave spectroscopy.

Park, G. B., & Field, R. W. (2016). Perspective: The first ten years of broadband chirped pulse Fourier transform microwave spectroscopy. Journal of Chemical Physics, 144(20): 200901. doi:10.1063/1.4952762.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002A-F366-D Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-0994-4
Genre: Journal Article

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2308928.pdf (Publisher version), 2MB
 
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 Creators:
Park, G. B.1, Author              
Field, R. W., Author
Affiliations:
1Department of Dynamics at Surfaces, MPI for Biophysical Chemistry, Max Planck Society, ou_578600              

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Free keywords: Microwave spectroscopy; Microwave spectra; Chirping; Microwave spectrometers; Polarization
 Abstract: Since its invention in 2006, the broadband chirped pulse Fourier transform spectrometer has transformed the field of microwave spectroscopy. The technique enables the collection of a >= 10 GHz bandwidth spectrum in a single shot of the spectrometer, which allows broadband, high-resolution microwave spectra to be acquired several orders of magnitude faster than what was previously possible. We discuss the advantages and challenges associated with the technique and look back on the first ten years of chirped pulse Fourier transform spectroscopy. In addition to enabling faster-than-ever structure determination of increasingly complex species, the technique has given rise to an assortment of entirely new classes of experiments, ranging from chiral sensing by three-wave mixing to microwave detection of multichannel reaction kinetics. However, this is only the beginning. Future generations of microwave experiments will make increasingly creative use of frequency-agile pulse sequences for the coherent manipulation and interrogation of molecular dynamics.

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Language(s): eng - English
 Dates: 2016-05-272016-05-28
 Publication Status: Published in print
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 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1063/1.4952762
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Title: Journal of Chemical Physics
Source Genre: Journal
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Pages: 10 Volume / Issue: 144 (20) Sequence Number: 200901 Start / End Page: - Identifier: -