English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
EndNote (UTF-8)
 
DownloadE-Mail
 Local TagsRelease HistoryDetailsSummary
  Selective Aromatic C-H Hydroxylation Enabled by η6-Coordination to Iridium(III)

D'Amato, E. M., Neumann, C. N., & Ritter, T. (2015). Selective Aromatic C-H Hydroxylation Enabled by η6-Coordination to Iridium(III). Organometallics, 34(18), 4626-4631. doi:10.1021/acs.organomet.5b00731.

Item is

 

show all

Basic

hide
Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002B-9FF8-1 Version Permalink: https://hdl.handle.net/21.11116/0000-0008-DBAB-1
Genre: Journal Article

Files

show Files

Locators

show

Creators

hide
 Creators:
D'Amato, Erica M.1, Author
Neumann, Constanze N.1, Author           
Ritter, Tobias1, Author           
Affiliations:
1Department for Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA, ou_persistent22              

Content

hide
Free keywords: -
 Abstract: We report an aromatic C–H hydroxylation protocol in which the arene is activated through η6-coordination to an iridium(III) complex. η6-Coordination of the arene increases its electrophilicity and allows for high positional selectivity of hydroxylation at the site of least electron density. Through investigation of intermediate η5-cyclohexadienyl adducts and arene exchange reaction, we evaluate incorporation of arene π-activation into a catalytic cycle for C–H functionalization.

Details

hide
Language(s): eng - English
 Dates: 2015-08-252015-09-162015-09-28
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/acs.organomet.5b00731
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

hide
Title: Organometallics
  Abbreviation : Organometallics
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Washington, D.C. : American Chemical Society
Pages: - Volume / Issue: 34 (18) Sequence Number: - Start / End Page: 4626 - 4631 Identifier: ISSN: 0276-7333
CoNE: https://pure.mpg.de/cone/journals/resource/954925505259