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  Shock wave and modeling study of the reaction CF4 (+ M) <--> CF3 + F (+ M).

Knight, G., Sölter, L., Tellbach, E., & Troe, J. (2016). Shock wave and modeling study of the reaction CF4 (+ M) <--> CF3 + F (+ M). Physical Chemistry Chemical Physics, 18(26), 17592-17596. doi:10.1039/C6CP03010F.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002B-0441-B Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-CF23-6
Genre: Journal Article

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2315975.pdf (Publisher version), 2MB
 
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 Creators:
Knight, G., Author
Sölter, L.1, Author              
Tellbach, E.2, Author              
Troe, J.1, Author              
Affiliations:
1Emeritus Group of Spectroscopy and Photochemical Kinetics, MPI for Biophysical Chemistry, Max Planck Society, ou_578625              
2Department of Dynamics at Surfaces, MPI for Biophysical Chemistry, Max Planck Society, ou_578600              

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 Abstract: The thermal decomposition of CF4 (+Ar) → CF3 + F (+Ar) was studied in shock waves over the temperature range 2000–3000 K varying the bath gas concentration [Ar] between 4 × 10−6 and 9 × 10−5 mol cm−3. It is shown that the reaction corresponds to the intermediate range of the falloff curve. By combination with room temperature data for the reverse reaction CF3 + F (+He) → CF4 (+He) and applying unimolecular rate theory, falloff curves over the temperature range 300–6000 K are modeled. A comparison with the reaction system CH4 (+M) ⇔ CH3 + H (+M) is made.

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Language(s): eng - English
 Dates: 2016-06-082016-07-14
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1039/C6CP03010F
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Title: Physical Chemistry Chemical Physics
Source Genre: Journal
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Pages: - Volume / Issue: 18 (26) Sequence Number: - Start / End Page: 17592 - 17596 Identifier: -