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  An Approach to Highly Hindered BINOL Phosphates

Monaco, M. R., Properzi, R., & List, B. (2016). An Approach to Highly Hindered BINOL Phosphates. Synlett, 27(4), 591-594. doi:10.1055/s-0035-1560771.

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 Creators:
Monaco, Mattia Ricardo1, Author              
Properzi, Roberta1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: phosphoric acids; confined catalysts; asymmetric organocatalysis; biaryl synthesis; aryne coupling reaction
 Abstract: The synthesis of 3-3′-substituted BINOL-derived chiral phosphoric acid catalysts is still largely limited by the limitations of current cross-coupling methodologies. For this reason, despite the importance of sterically demanding catalysts in Brønsted acid catalysis, highly hindered congeners are still unprecedented. Exploiting the aryne addition reaction as key step, we report herein the development of a novel synthetic route to access this unexplored class of catalysts.

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Language(s): eng - English
 Dates: 2015-09-022015-09-302015-10-202016-03-01
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/s-0035-1560771
 Degree: -

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Title: Synlett
  Abbreviation : Synlett
Source Genre: Journal
 Creator(s):
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Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 27 (4) Sequence Number: - Start / End Page: 591 - 594 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856