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  2,5-dihydro-1H-1,2,4-triazol-2-yl radicals: syntheses and properties

Neugebauer, F. A., & Fischer, H. (1995). 2,5-dihydro-1H-1,2,4-triazol-2-yl radicals: syntheses and properties. Tetrahedron, 51(47), 12883-12898. doi:10.1016/0040-4020(95)00730-V.

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Genre: Journal Article
Alternative Title : 2,5-dihydro-1H-1,2,4-triazol-2-yl radicals: syntheses and properties

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Tetrahedron_51_1995_12883.pdf (Any fulltext), 2MB
 
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 Creators:
Neugebauer, Franz A.1, Author           
Fischer, Hans1, Author           
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1Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706              

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 Abstract: A range of 2,5-dihydro-1H-1,2,4-triazol-2-yl radicals 2b–p has been prepared by dehydrogenation of the corresponding 4,5-dihydro-1H-1,2,4-triazoles 5b–p which have been synthesized using various methods. EPR, ENDOR and NMR studies have led to a complete analysis and full assignment of all hyperfine coupling constants. The π-SOMO, having a node at the C(3) methine carbon, is mainly confined to the nitrogens of the five-membered ring, particularly to those of the hydrazyl moiety.

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Language(s): eng - English
 Dates: 1995-06-121995-09-081995-11-20
 Publication Status: Issued
 Pages: 16
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 Rev. Type: Peer
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Title: Tetrahedron
  Other : Tetrahedron
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: - Volume / Issue: 51 (47) Sequence Number: - Start / End Page: 12883 - 12898 Identifier: ISSN: 0040-4020
CoNE: https://pure.mpg.de/cone/journals/resource/954925448773