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  Halloysites Stabilized Emulsions for Hydroformylation of Long Chain Olefins

von Klitzing, R., Stehl, D., Pogrzeba, T., Schomäcker, R., Minullina, R., Panchal, A., et al. (2017). Halloysites Stabilized Emulsions for Hydroformylation of Long Chain Olefins. Advanced Materials Interfaces, 4(1): 1600435. doi:10.1002/admi.201600435.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002B-528D-8 Version Permalink: http://hdl.handle.net/21.11116/0000-0005-7914-D
Genre: Journal Article

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2344254.pdf (Publisher version), 2MB
 
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 Creators:
von Klitzing, Regine, Author
Stehl, Dimitrij, Author
Pogrzeba, Tobias, Author
Schomäcker, Reinhard, Author
Minullina, Renata, Author
Panchal, Abhishek, Author
Konnova, Svetlana, Author
Fakhrullin, Rawil, Author
Koetz, Joachim, Author
Möhwald, Helmuth1, Author              
Lvov, Yuri, Author
Affiliations:
1Grenzflächen, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863287              

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Free keywords: catalysis, clay nanotubes, oil spill, Pickering emulsions
 Abstract: Halloysites as tubular alumosilicates are introduced as inexpensive natural nanoparticles to form and stabilize oil–water emulsions. This stabilized emulsion is shown to enable efficient interfacial catalytic reactions. Yield, selectivity, and product separation can be tremendously enhanced, e.g., for the hydroformylation reaction of dodecene to tridecanal. In perspective, this type of formulation may be used for oil spill dispersions. The key elements of the described formulations are clay nanotubes (halloysites) which are highly anisometric, can be filled by helper molecules, and are abundantly available in thousands of tons, making this technology scalable for industrial applications.

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 Dates: 2016-09-072017-01-09
 Publication Status: Published in print
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 Identifiers: DOI: 10.1002/admi.201600435
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Title: Advanced Materials Interfaces
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 4 (1) Sequence Number: 1600435 Start / End Page: - Identifier: ISSN: 2196-7350