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  The plastic crystalline A15 phase of dimethylaminoalane, [N(CH3)2–AlH2]3

Ley, M. B., Bernert, T., Ruiz-Fuertes, J., Goddard, R., Farès, C., Weidenthaler, C., et al. (2016). The plastic crystalline A15 phase of dimethylaminoalane, [N(CH3)2–AlH2]3. Chemical Communications, 52(78), 11649-11652. doi:10.1039/C6CC06166D.

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 Creators:
Ley, M. B.1, Author           
Bernert, T.2, Author           
Ruiz-Fuertes, J.3, 4, Author
Goddard, R.5, Author           
Farès, C.6, Author           
Weidenthaler, C.2, Author           
Felderhoff, M.1, Author           
Affiliations:
1Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              
2Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1950291              
3Goethe-Universität Frankfurt am Main, Institut für Geowissenschaften, Abt. Kristallographie, Altenhöferallee 1, D-60438 Frankfurt am Main, Germany , ou_persistent22              
4Departament de Física Aplicada – ICMUV, Universitat de València, Dr. Moliner 50, E-46100 Burjassot, Spain, ou_persistent22              
5Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              
6Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445623              

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 Abstract: A plastic crystalline phase of dimethylaminoalane has been discovered at T > 332 K. The phase transitions solid – plastic phase – liquid are fully reversible. The plastic crystalline phase exhibits a cubic unit cell, space group Pm3̅ n, in which the dimethylaminoalane molecules rotate and adopt a structural arrangement reminiscent of the A15 phase.

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Language(s): eng - English
 Dates: 2016-07-262016-08-272016-08-302016-10-07
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C6CC06166D
 Degree: -

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Title: Chemical Communications
  Other : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 52 (78) Sequence Number: - Start / End Page: 11649 - 11652 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413