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  Unexpected Beneficial Effect of ortho-Substituents on the (S)-Proline-Catalyzed Asymmetric Aldol Reaction of Acetone with Aromatic Aldehydes

Martínez, A., van Gemmeren, M., & List, B. (2014). Unexpected Beneficial Effect of ortho-Substituents on the (S)-Proline-Catalyzed Asymmetric Aldol Reaction of Acetone with Aromatic Aldehydes. Synlett, 25(7), 961-964. doi:10.1055/s-0033-1340920.

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 Creators:
Martínez, Alberto1, Author              
van Gemmeren, Manuel1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: aldehyde; aldol reaction; asymmetric catalysis; organocatalysis; proline
 Abstract: An intriguing effect of electronegative 2,6-substituents on the stereochemical outcome of (S)-proline-catalyzed aldol reactions between benzaldehyde derivatives and acetone is reported. Remarkably high enantioselectivities can be achieved with such substrates.

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Language(s): eng - English
 Dates: 2014-02-042014-02-162014-03-252014-04-01
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/s-0033-1340920
 Degree: -

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Title: Synlett
  Abbreviation : Synlett
Source Genre: Journal
 Creator(s):
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Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 25 (7) Sequence Number: - Start / End Page: 961 - 964 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856