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  Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping

Miao, X. F., Thang, N. V., Caron, L., Yibole, H., Smith, R. I., van Dijk, N. H., et al. (2016). Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping. Scripta Materialia, 124, 129-132. doi:10.1016/j.scriptamat.2016.07.015.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002B-9B55-F Version Permalink: http://hdl.handle.net/21.11116/0000-0001-9C81-D
Genre: Journal Article

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 Creators:
Miao, X. F.1, Author
Thang, N. V.1, Author
Caron, L.2, Author              
Yibole, H.1, Author
Smith, R. I.1, Author
van Dijk, N. H.1, Author
Bruck, E.1, Author
Affiliations:
1External Organizations, ou_persistent22              
2Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              

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 Abstract: The critical temperature and first-order character of the magnetoelastic transition in (Mn,Fe)(2)(P,Si) are tunable by doping the structure with B, C and N atoms. Neutron diffraction experiments reveal that B substitutes Si on the lb site of the hexagonal P-62m structure, C occupies the interstitial 6j and 6k sites, while N distributes on both the lb and interstitial 6j and 6k sites. The tuning mechanism has been discussed in terms of the subtle variations in electronic configuration around the Fe atoms, which can be used to tailor the magnetoelastic transition. (C) 2016 Elsevier Ltd. All rights reserved.

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Language(s): eng - English
 Dates: 2016-07-202016-07-20
 Publication Status: Published in print
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 Table of Contents: -
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Title: Scripta Materialia
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier B. V.
Pages: - Volume / Issue: 124 Sequence Number: - Start / End Page: 129 - 132 Identifier: ISSN: 1359-6462
CoNE: /journals/resource/954926243506