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  Chemo- and Regioselective Functionalization of Polyols through Catalytic C(sp3)–C(sp3) Kumada-Type Coupling of Cyclic Sulfate Esters

Ramírez-Contreras, R., & Morandi, B. (2016). Chemo- and Regioselective Functionalization of Polyols through Catalytic C(sp3)–C(sp3) Kumada-Type Coupling of Cyclic Sulfate Esters. Organic Letters, 18(15), 3718-3721. doi:10.1021/acs.orglett.6b01745.

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 Creators:
Ramírez-Contreras, Rodrigo1, Author           
Morandi, Bill1, Author           
Affiliations:
1Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309              

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 Abstract: This contribution describes a copper-catalyzed, C(sp3)–C(sp3) cross-coupling reaction of cyclic sulfate esters, a distinct class of electrophilic derivatives of polyols, with alkyl Grignard reagents to afford functionalized alcohol products in good yields. The method is operationally simple and highlights the potential of cyclic sulfate esters as highly reactive substrates in catalytic, chemoselective polyol transformations.

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Language(s): eng - English
 Dates: 2016-06-162016-07-212016-08-05
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/acs.orglett.6b01745
 Degree: -

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Title: Organic Letters
  Other : Org. Lett.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: 4 Volume / Issue: 18 (15) Sequence Number: - Start / End Page: 3718 - 3721 Identifier: ISSN: 1523-7060
CoNE: https://pure.mpg.de/cone/journals/resource/954925626338