English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Synthesis of Bidimensional Prussian Blue Analogue Using an Inverted Langmuir–Schaefer Method

Rossos, A., Gengler, R. Y. N., Badali, D. S., & Miller, R. J. D. (2016). Synthesis of Bidimensional Prussian Blue Analogue Using an Inverted Langmuir–Schaefer Method. Langmuir, 32(38), 9706-9713. doi:10.1021/acs.langmuir.6b02445.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002B-B8DE-0 Version Permalink: http://hdl.handle.net/21.11116/0000-0001-EFE6-F
Genre: Journal Article

Files

show Files
hide Files
:
acs.langmuir.6b02445.pdf (Publisher version), 5MB
 
File Permalink:
-
Name:
acs.langmuir.6b02445.pdf
Description:
-
Visibility:
Private
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show
hide
Locator:
http://dx.doi.org/10.1021/acs.langmuir.6b02445 (Publisher version)
Description:
-

Creators

show
hide
 Creators:
Rossos, Andreas1, 2, Author              
Gengler, Régis Y. N.1, 2, Author              
Badali, Daniel S.1, 2, Author              
Miller, R. J. Dwayne1, 2, 3, Author              
Affiliations:
1Miller Group, Atomically Resolved Dynamics Department, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society, ou_1938288              
2Center for Free Electron Laser Science, The Hamburg Centre for Ultrafast Imaging (CUI), Universität Hamburg, Luruper Chaussee 149, 22761 Hamburg, Germany, ou_persistent22              
3Departments of Chemistry and Physics, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada, ou_persistent22              

Content

show
hide
Free keywords: -
 Abstract: One of the aspects of modern materials science that has been captivating scientific interest for the past decade is low-dimensional systems. This stems from the fact that the physical, chemical, and biological properties of such systems are often vastly different from their bulk counterparts. Additionally, low-dimensionality structures frequently serve as a convenient platform for device applications. However, such materials are typically constructed from building blocks that are inherently three-dimensional, and so, from a morphological point of view, these can still be categorized as bulk powders or crystals. To push the boundaries of reduced dimensionality, we synthesized truly two-dimensional films of Prussian blue analogues (mixed valence tetracyanides) by combining an air–water interface reaction and a novel inverted Langmuir–Schaefer technique. The methodology introduced in this study offers control and tailoring over the Prussian blue analogues’ film characteristics, which is an important step toward their incorporation into tangible applications. Standard isotherms were collected as a function of the initial reactant volume, and a number of characterization techniques such as X-ray photoelectron spectroscopy (XPS), UV–visible spectroscopy (UV–vis), transmission electron microscopy (TEM), selected area electron diffraction (SAED), and atomic force microscopy (AFM) were performed on films transferred on various substrates. The results indicated a collection of single-crystalline and polycrystalline flakes possessing different thicknesses and having a structural coherence length of 11 ± 3 nm.

Details

show
hide
Language(s): eng - English
 Dates: 2016-07-012016-09-072016-09-27
 Publication Status: Published in print
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1021/acs.langmuir.6b02445
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Langmuir
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Columbus, OH : American Chemical Society
Pages: - Volume / Issue: 32 (38) Sequence Number: - Start / End Page: 9706 - 9713 Identifier: ISSN: 0743-7463
CoNE: /journals/resource/954925541194