English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  Communication: Structural locking mediated by a water wire: A high-resolution rotational spectroscopy study on hydrated forms of a chiral biphenyl derivative

Domingos, S. R., Pérez, C., & Schnell, M. (2016). Communication: Structural locking mediated by a water wire: A high-resolution rotational spectroscopy study on hydrated forms of a chiral biphenyl derivative. The Journal of Chemical Physics, 145(16): 161103. doi:10.1063/1.4966584.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002B-B92F-0 Version Permalink: https://hdl.handle.net/21.11116/0000-0004-93A9-7
Genre: Journal Article

Files

show Files
hide Files
:
1.4966584.pdf (Publisher version), 2MB
View   Save
File Permalink:
https://hdl.handle.net/11858/00-001M-0000-002B-B931-8
Name:
1.4966584.pdf
Description:
-
OA-Status:
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
View
Copyright Date:
2016
Copyright Info:
© the Author(s)
License:
https://publishing.aip.org/resources/researchers/rights-and-permissions/sharing-content-online/
:
Domingos_et_al_bpco_water_SI.pdf (Supplementary material), 361KB
View   Save
File Permalink:
https://hdl.handle.net/11858/00-001M-0000-002B-B932-6
Name:
Domingos_et_al_bpco_water_SI.pdf
Description:
-
OA-Status:
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
View
Copyright Date:
2016
Copyright Info:
© the Author(s)
License:
https://publishing.aip.org/resources/researchers/rights-and-permissions/sharing-content-online/

Locators

show
hide
Locator:
http://dx.doi.org/10.1063/1.4966584 (Publisher version)
Description:
-
OA-Status:

Creators

show
hide
 Creators:
Domingos, Sérgio R.1, 2, 3, Author           
Pérez, Cristóbal1, 2, 3, Author           
Schnell, Melanie1, 2, 3, Author           
Affiliations:
1Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society, ou_1938292              
2Center for Free-Electron Laser Science, Luruper Chaussee 149, 22761 Hamburg, Germany, ou_persistent22              
3The Hamburg Centre for Ultrafast Imaging, Universität Hamburg, Luruper Chaussee 149, 22761 Hamburg, Germany, ou_persistent22              

Content

show
hide
Free keywords: Water energy interactions; Chiral symmetries; Broadband transmission; Hydrogen bonding; Rotation constants
 Abstract: We report the observation of structural changes in an axially chiral molecule, biphenyl-2-carboxaldehyde, due to aggregation with water. Using high-resolution broadband rotational spectroscopy we find that two water molecules link opposite sides of the molecule, resembling a water wire. We show that this effect can be explained by a cooperative rearrangement of both molecule and a water dimer. Hydrogen bonding interactions are shown to change the original structure upon aggregation of water. This phenomenon is insightful on the role of microsolvation in assisting structural morphing of stereo-selective chiral molecular systems.

Details

show
hide
Language(s): eng - English
 Dates: 2016-08-262016-10-102016-10-282016-10-28
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1063/1.4966584
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: The Journal of Chemical Physics
  Other : J. Chem. Phys.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Woodbury, N.Y. : American Institute of Physics
Pages: - Volume / Issue: 145 (16) Sequence Number: 161103 Start / End Page: - Identifier: ISSN: 0021-9606
CoNE: https://pure.mpg.de/cone/journals/resource/954922836226