Deutsch
 
Hilfe Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT
Zur Ablage hinzufügen
 DetailsÜbersicht
  The role of nonmagnetic d0 vs. d10 B-type cations on the magnetic exchange interactions in osmium double perovskites

Feng, H. L., Yamaura, K., Tjeng, L.-H., & Jansen, M. (2016). The role of nonmagnetic d0 vs. d10 B-type cations on the magnetic exchange interactions in osmium double perovskites. European Journal of Solid State and Inorganic Chemistry, 243, 119-123. doi:10.1016/j.jssc.2016.08.022.

Item is

 

einblenden: alle ausblenden: alle

Basisdaten

einblenden: ausblenden:
Datensatz-Permalink: https://hdl.handle.net/11858/00-001M-0000-002B-B99B-D Versions-Permalink: https://hdl.handle.net/11858/00-001M-0000-002D-B375-1
Genre: Zeitschriftenartikel

Externe Referenzen

einblenden:

Urheber

einblenden:
ausblenden:
 Urheber:
Feng, Hai L.1, Autor           
Yamaura, Kazunari2, Autor
Tjeng, Liu-Hao3, Autor           
Jansen, Martin4, Autor           
Affiliations:
1Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863445              
2External Organizations, ou_persistent22              
3Liu Hao Tjeng, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863452              
4Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              

Inhalt

einblenden:
ausblenden:
Schlagwörter: -
 Zusammenfassung: Polycrystalline samples of double perovskites Ba2BOsO6 (B=Sc, Y, In) were synthesized by solid state reactions. They adopt the cubic double perovskite structures (space group, Fm-3m) with ordered B and Os arrangements. Ba2BOsO6 (B=Sc, Y, In) show antiferromagnetic transitions at 93 K, 69 K, and 28 K, respectively. The Weiss-temperatures are -590 K for Ba2BOsO6, -571 K for Ba2BOsO6, and -155 K for Ba2BOsO6.Sc3+ and Y3+ have the open-shell d(0) electronic configuration, while In3+ has the closed-shell d(10). This indicates that a d(0) B-type cation induces stronger overall magnetic exchange interactions in comparison to a d(10). Comparison of Ba2BOsO6 (B=Sc, Y, In) to their Sr and Ca analogues shows that the structural distortions weaken the overall magnetic exchange interactions. (C) 2016 Elsevier Inc. All rights reserved.

Details

einblenden:
ausblenden:
Sprache(n): eng - English
 Datum: 2016-08-182016-08-18
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: ISI: 000384874100019
DOI: 10.1016/j.jssc.2016.08.022
 Art des Abschluß: -

Veranstaltung

einblenden:

Entscheidung

einblenden:

Projektinformation

einblenden:

Quelle 1

einblenden:
ausblenden:
Titel: European Journal of Solid State and Inorganic Chemistry
  Andere : Eur. J. Solid State Inorg. Chem.
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: Paris : Elsevier Masson SAS
Seiten: - Band / Heft: 243 Artikelnummer: - Start- / Endseite: 119 - 123 Identifikator: ISSN: 0992-4361
CoNE: https://pure.mpg.de/cone/journals/resource/954928508624