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  Cultured roots of Xiphidium caeruleum: Phenylphenalenones and their biosynthetic and extractant-dependent conversion

Chen, Y., Paetz, C., Menezes, R. C., & Schneider, B. (2017). Cultured roots of Xiphidium caeruleum: Phenylphenalenones and their biosynthetic and extractant-dependent conversion. Phytochemistry, 133, 15-25. doi:10.1016/j.phytochem.2016.10.011.

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NMR237s1.pdf (Supplementary material), 2MB
 
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 Creators:
Chen, Yu1, Author           
Paetz, Christian1, Author           
Menezes, Riya Christina2, Author           
Schneider, Bernd1, Author           
Affiliations:
1Research Group Biosynthesis / NMR, MPI for Chemical Ecology, Max Planck Society, ou_421898              
2Research Group Mass Spectrometry, MPI for Chemical Ecology, Max Planck Society, ou_421899              

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 Abstract: Phytochemical investigation of root cultures of Xiphidium caeruleum (Haemodoraceae) resulted in the structure elucidation of five previously undescribed phenylphenalenone-type compounds, structure revision of a phenylphenalenone glucoside, and identification of nine additional constituents previously reported from other Haemodoraceae and Musaceae plants. The observed extractant-dependent metabolic profiles indicated that phenylphenalenones had been converted hydrolytically and oxidatively. Stable isotope labeling experiments extended the understanding of the phenylphenalenone pathway in plants and provided evidence for a network of biosynthetic and spontaneous conversions linking phenylphenalenones and their derivatives detected in extracts of cultured roots of this plant.

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 Dates: 2016-10-272016-11-022017
 Publication Status: Published in print
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 Identifiers: Other: NMR237
DOI: 10.1016/j.phytochem.2016.10.011
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Title: Phytochemistry
  Other : Phyto
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: - Volume / Issue: 133 Sequence Number: - Start / End Page: 15 - 25 Identifier: ISSN: 0031-9422
CoNE: https://pure.mpg.de/cone/journals/resource/954925433416