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  Synthesis and characterization of copper(II) complexes incorporating pyrazolyl-derived N,S-donor bidentate ligands.

Sadr, M. H., Soltani, B., Jalili, A., Nejadghafar, F., Kia, R., Engle, J. T., et al. (2012). Synthesis and characterization of copper(II) complexes incorporating pyrazolyl-derived N,S-donor bidentate ligands. Transition Metal Chemistry, 37(7), 611-617. doi:10.1007/s11243-012-9629-9.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-01EC-7 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-01EF-1
Genre: Journal Article

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2364675.pdf (Publisher version), 447KB
 
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Sadr, M. H., Author
Soltani, B., Author
Jalili, A., Author
Nejadghafar, F., Author
Kia, R.1, Author              
Engle, J. T., Author
Ziegler, C. J., Author
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1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

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 Abstract: The novel bidentate N,S-donor anionic ligands [PhNCSIndz]−, [PhNCSImz]−, [PhNCSPzMe3]−, and [EtNCSPz]−, where Indz = indazole, Imz = imidazole, PzMe3 = 3,4,5-trimethylpyrazole, and Pz = pyrazole, were synthesized and used to prepare Cu(II) complexes of general formula [Cu(N^S)2]. The ligands were synthesized via direct addition of phenylisothiocyanate or ethylisothiocyanate into THF suspensions of the corresponding sodium-pyrazolate salts. All of the synthesized compounds, including the ligands and the complexes, were characterized by physico-chemical and spectroscopic methods, and crystal structures of [Cu(EtNCSPz)2] and [Cu(PhNCSPzMe2)2] were determined by X-ray diffraction analysis, showing a trans-square planar geometry for [Cu(EtNCSPz)2] and a distorted tetrahedral geometry for [Cu(PhNCSPzMe2)2].

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Language(s): eng - English
 Dates: 2012-07-182012-10
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1007/s11243-012-9629-9
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Title: Transition Metal Chemistry
Source Genre: Journal
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Pages: - Volume / Issue: 37 (7) Sequence Number: - Start / End Page: 611 - 617 Identifier: -