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  {4,4'-Dimethyl-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate.

Kargar, H., Kia, R., Ganji, F., & Mirkhani, V. (2012). {4,4'-Dimethyl-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate. Acta Crystallographica Section E, 68(9): m1172. doi:10.1107%2FS1600536812034502.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-0B67-1 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-2462-6
Genre: Journal Article

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2366930.pdf (Publisher version), 361KB
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Kargar, H., Author
Kia, R.1, Author              
Ganji, F., Author
Mirkhani, V., Author
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1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

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 Abstract: The asymmetric unit of the title compound, [Cu(C21H24N2O2)]·H2O, comprises half of a Schiff base complex and half of a water mol­ecule. The whole compound is generated by crystallographic twofold rotation symmetry. The geometry around the CuII atom, located on a twofold axis, is distorted square-planar, which is supported by the N2O2 donor atoms of the coordinating Schiff base ligand. The dihedral angle between the symmetry-related benzene rings is 47.5 (4)°. In the crystal, the water mol­ecule that is hydrogen bonded to the coordinated O atoms links the mol­ecules via O—H⋯O inter­actions into chains parallel to [001]. The crystal structure is further stabilized by C—H⋯π inter­actions, and by π–π inter­actions involving inversion-related chelate rings [centroid–centroid distance = 3.480 (4) Å].

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Language(s): eng - English
 Dates: 2012-08-112012-09-01
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1107%2FS1600536812034502
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Title: Acta Crystallographica Section E
Source Genre: Journal
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Pages: 8 Volume / Issue: 68 (9) Sequence Number: m1172 Start / End Page: - Identifier: -