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  A Cu(ii) metal-organic framework as a recyclable catalyst for ARGET ATRP

Lee, H.-C., Antonietti, M., & Schmidt, B. V. K. J. (2016). A Cu(ii) metal-organic framework as a recyclable catalyst for ARGET ATRP. Polymer Chemistry, 7(47), 7199-7203. doi:10.1039/C6PY01844K.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-0F8A-2 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-0F8B-F
Genre: Journal Article

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 Creators:
Lee, Hui-Chun1, Author              
Antonietti, Markus2, Author              
Schmidt, Bernhard V. K. J.1, Author              
Affiliations:
1Bernhard Schmidt, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_2149676              
2Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863321              

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Free keywords: Open Access
 Abstract: A Cu(ii) MOF can serve as an efficient catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP), e.g. for the synthesis of poly(benzyl methacrylate) (PBzMA) and polystyrene (PS). Furthermore, poly(isoprene) (PI) and poly(4-vinylpyridine) (P4VP) can be formed in a controlled fashion as well, which used to be challenging to achieve by traditional strategies. Taking advantage of the heterogeneous nature of the catalyst, recycling via centrifugation and repeated utilization for at least six cycles are demonstrated.

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 Dates: 2016
 Publication Status: Published in print
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 Identifiers: DOI: 10.1039/C6PY01844K
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Title: Polymer Chemistry
  Abbreviation : Polym. Chem.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 7 (47) Sequence Number: - Start / End Page: 7199 - 7203 Identifier: ISSN: 1759-9954