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  Organoplatinum(II) complexes containing chelating or bridging bis(N-heterocyclic carbene) ligands: Formation of a platinum(II) carbonate complex by aerial CO2 fixation.

Jamali, S., Milić, D., Kia, R., Mazloomi, Z., & Abdolahi, H. (2011). Organoplatinum(II) complexes containing chelating or bridging bis(N-heterocyclic carbene) ligands: Formation of a platinum(II) carbonate complex by aerial CO2 fixation. Dalton Transactions, 40(37), 9362-9365. doi:10.1039/c1dt10736d.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-17C7-2 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-17CB-9
Genre: Journal Article

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2368734.pdf (Publisher version), 952KB
 
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 Creators:
Jamali, S., Author
Milić, D., Author
Kia, R.1, Author              
Mazloomi, Z., Author
Abdolahi, H., Author
Affiliations:
1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

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 Abstract: The preparation of two new bis(N-heterocyclic carbene) platinum(II) complexes, in which NHC rings are joined by a CH(2) linker group, is described. While, the chelate complex [PtMe(2)(bis-NHC1)], 1, was formed with large tert-butyl wingtips, the iso-propyl N-substituent analogue favors formation of the cluster complex [Pt(2)Me(4)(μ-SMe(2))(μ-bis-NHC2)](2)(μ-Ag(2)Br(2)), 2, in which two binuclear platinum(II) complexes are linked together by an Ag(2)Br(2) unit. The chelating platinum complex 1 undergoes aerial CO(2) fixation and forms platinum(II) carbonate complex [Pt(CO(3))(bis-NHC1)], 3.

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Language(s): eng - English
 Dates: 2011-06-092011-10-07
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1039/c1dt10736d
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Title: Dalton Transactions
Source Genre: Journal
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Pages: - Volume / Issue: 40 (37) Sequence Number: - Start / End Page: 9362 - 9365 Identifier: -