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  Chirped-pulse Fourier transform millimeter-wave spectroscopy of ten vibrationally excited states of i-propyl cyanide: exploring the far-infrared region

Arenas, B., Gruet, S., Steber, A. L., Giuliano, B. M., & Schnell, M. (2017). Chirped-pulse Fourier transform millimeter-wave spectroscopy of ten vibrationally excited states of i-propyl cyanide: exploring the far-infrared region. Physical Chemistry Chemical Physics, 19(3), 1751-1756. doi:10.1039/C6CP06297K.

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Datensatz-Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-1890-3 Versions-Permalink: http://hdl.handle.net/21.11116/0000-0001-E256-F
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2017
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externe Referenz:
https://dx.doi.org/10.1039/C6CP06297K (Verlagsversion)
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 Urheber:
Arenas, Benjamin1, 2, 3, Autor              
Gruet, Sébastien2, 3, 4, Autor              
Steber, Amanda L.2, 3, 4, Autor              
Giuliano, Barbara Michela5, Autor              
Schnell, Melanie2, 3, 4, Autor              
Affiliations:
1International Max Planck Research School for Ultrafast Imaging & Structural Dynamics (IMPRS-UFAST), Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society, ou_2266714              
2Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society, ou_1938292              
3Center for Free-Electron Laser Science, Notkestrasse 85, D-22607 Hamburg, Germany, ou_persistent22              
4The Hamburg Centre for Ultrafast Imaging, Luruper Chaussee 149, D-22761 Hamburg, Germany, ou_persistent22              
5Center for Astrochemical Studies at MPE, MPI for Extraterrestrial Physics, Max Planck Society, ou_1950287              

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 Zusammenfassung: We report here further spectroscopic investigation of the astrochemically relevant molecule i-propyl cyanide. We observed and analysed the rotational spectra of the ground state of the molecule and ten vibrationally excited states with energies between 180–500 cm−1. For this, we used a segmented W-band spectrometer (75–110 GHz) and performed the experiments under room temperature conditions. This approach thus provides access to high-resolution, pure rotational data of vibrational modes that occur in the far-infrared fingerprint region, and that can be difficult to access with other techniques. The obtained, extensive data set will support further astronomical searches and identifications, such as in warmer regions of the interstellar space where contributions from vibrationally excited states become increasingly relevant.

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Sprache(n): eng - Englisch
 Datum: 2016-09-132016-09-262016-10-252017-01-21
 Publikationsstatus: Im Druck publiziert
 Seiten: 6
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: DOI: 10.1039/C6CP06297K
 Art des Abschluß: -

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Projektinformation

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Projektname : ASTROROT
Grant ID : 638027
Förderprogramm : Horizon 2020 (H2020)
Förderorganisation : European Commission (EC)

Quelle 1

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Titel: Physical Chemistry Chemical Physics
  Kurztitel : Phys. Chem. Chem. Phys.
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: Cambridge, England : Royal Society of Chemistry
Seiten: - Band / Heft: 19 (3) Artikelnummer: - Start- / Endseite: 1751 - 1756 Identifikator: ISSN: 1463-9076
CoNE: /journals/resource/954925272413_1