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  A cyclopalladated phosphine selenide with an anionic acylselenourea ligand

Molter, A., Rust, J., Lehmann, C. W., & Mohr, F. (2016). A cyclopalladated phosphine selenide with an anionic acylselenourea ligand. Inorganic Chemistry Communications, 73(11), 69-71. doi:10.1016/j.inoche.2016.09.016.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002C-1975-A Version Permalink: https://hdl.handle.net/11858/00-001M-0000-002C-1976-8
Genre: Journal Article

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 Creators:
Molter, Anja1, Author
Rust, Jörg2, Author           
Lehmann, Christian W.2, Author           
Mohr, Fabian1, Author
Affiliations:
1Fakultät für Mathematik und Naturwissenschaften, Anorganische Chemie, Bergische Universität Wuppertal, 42119 Wuppertal, Germany, ou_persistent22              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: Selenium; Palladium; Cyclometallation; Phosphine selenide; Selenourea; X-ray structure
 Abstract: The chloro-bridged cyclometallated palladium(II) complex [PdCl{κC,Se-C6H4P(Se)Ph2}]2 reacts with 4-MeC6H4C(O)NHC(Se)NEt2 in the presence of base to give [Pd{κC,Se-C6H4P(Se)Ph2}{κO,Se-4- MeC6H4C(O)NC(Se)NEt2}] in high yield. The complex was fully characterised by spectroscopic methods and also X-ray diffraction. This compound represents one of the few examples of a metal complex containing two different selenium-containing ligands.

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Language(s): eng - English
 Dates: 2016-09-122016-08-152016-09-172016-09-212016-11
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/j.inoche.2016.09.016
 Degree: -

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Title: Inorganic Chemistry Communications
  Other : Inorg. Chem. Commun.
Source Genre: Journal
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Publ. Info: New York, NY : Elsevier
Pages: - Volume / Issue: 73 (11) Sequence Number: - Start / End Page: 69 - 71 Identifier: ISSN: 1387-7003
CoNE: https://pure.mpg.de/cone/journals/resource/954925406710