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  Aqua{4,4′,6,6′-tetra­chloro-2,2′-[(2,2-di­methylpropane-1,3-diyl)bis­(nitrilomethanylyl­idene)]diphenolato}zinc.

Kargar, H., Kia, R., Adabi Ardakani, A., & Tahir, M. N. (2012). Aqua{4,4′,6,6′-tetra­chloro-2,2′-[(2,2-di­methylpropane-1,3-diyl)bis­(nitrilomethanylyl­idene)]diphenolato}zinc. Acta Crystallographica Section E, 68(7): m936-m937. doi:10.1107/S1600536812025986.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-208E-8 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-2093-7
Genre: Journal Article

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 Creators:
Kargar, H., Author
Kia, R.1, Author              
Adabi Ardakani, A. , Author
Tahir, M. N., Author
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1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

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 Abstract: The asymmetric unit of the title compound, [Zn(C19H16Cl4N2O2)(H2O)], comprises two crystallographically independent mol­ecules. The geometry around the ZnII atoms is distorted trigonal–bipyramidal, supported by the N2O2 donor atoms of the tetradentate Schiff base and a coordinating water mol­ecule. The dihedral angles between the benzene rings in the two mol­ecules are 34.10 (15) Å and 30.61 (15) Å. In the crystal, neighbouring independent mol­ecules are linked by pairs of O—H⋯O hydrogen bonds, forming dimers with R22(6) ring motifs, and by O—H⋯Cl hydrogen bonds. There are short Cl⋯Cl [3.4728 (16), 3.4863 (16), and 3.388 (1) Å] contacts present, and mol­ecules are also linked by C—H⋯O and π–π [centroid–centroid distance = 3.671 (2) Å] inter­actions.

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Language(s): eng - English
 Dates: 2012-062012-07
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1107/S1600536812025986
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Title: Acta Crystallographica Section E
Source Genre: Journal
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Pages: 13 Volume / Issue: 68 (7) Sequence Number: m936-m937 Start / End Page: - Identifier: -