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  The nature of the excited states of p-nitro-N,N-dimethylaniline.

Dobkowski, J., Herbich, J., Waluk, J., Koput, J., & Kühnle, W. (1989). The nature of the excited states of p-nitro-N,N-dimethylaniline. Journal of Luminescence, 44(3), 149-160. doi:10.1016/0022-2313(89)90050-1.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-28B7-C Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-28BA-6
Genre: Journal Article

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2376603.pdf (Publisher version), 839KB
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Dobkowski, J., Author
Herbich, J., Author
Waluk, J., Author
Koput, J., Author
Kühnle, W.1, Author              
Affiliations:
1Department of Spectroscopy and Photochemical Kinetics, MPI for biophysical chemistry, Max Planck Society, ou_578624              

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 Abstract: Contrary to numerous derivatives of p-substituted N,N-dimethyl-aniline, p-nitro-N,N-dimethylaniline, does not form the TICT state. This behaviour is predicted by INDO/S calculations. The calculations also reveal an important role of the Coulomb interaction term in the evolution of intramolecular charge-transfer excited-state energy upon twisting of the dimethylamino group.

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Language(s): eng - English
 Dates: 1989-11
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1016/0022-2313(89)90050-1
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Title: Journal of Luminescence
Source Genre: Journal
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Pages: - Volume / Issue: 44 (3) Sequence Number: - Start / End Page: 149 - 160 Identifier: -