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  Solvent influence on the magnetic field effect of polymethylene‐linked photogenerated radical ion pairs.

Busmann, H. G., Staerk, H., & Weller, A. (1989). Solvent influence on the magnetic field effect of polymethylene‐linked photogenerated radical ion pairs. The Journal of Chemical Physics, 91(7), 4098-4105. doi:10.1063/1.457624.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-2B55-0 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-2B58-A
Genre: Journal Article

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2377018.pdf (Publisher version), 707KB
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Busmann, H. G., Author
Staerk, H.1, Author              
Weller, A.2, Author              
Affiliations:
1Department of Spectroscopy and Photochemical Kinetics, MPI for biophysical chemistry, Max Planck Society, ou_578624              
2Abteilung Spektroskopie, MPI for biophysical chemistry, Max Planck Society, ou_578545              

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 Abstract: The solvent viscosity and polarity dependence of the magnetic field effect in polymethylene‐linked radical ion pairs, which were generated by photoinduced intramolecular electron transfer in compounds of the type pyrene–(CH2)n–N,N‐dimethylaniline, has been studied. A stochastic Liouville equation is used, in which the dynamics of the polymethylene chain, the spin Hamiltonian as a function of the varying radical distance (exchange interaction), and a distance‐dependent back electron transfer rate are incorporated. The results are compared with predictions made on the basis of the (static) subensemble approximation.

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Language(s): eng - English
 Dates: 1989-10-01
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1063/1.457624
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Title: The Journal of Chemical Physics
Source Genre: Journal
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Pages: - Volume / Issue: 91 (7) Sequence Number: - Start / End Page: 4098 - 4105 Identifier: -