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  Swelling-Induced Deformation of Spherical Latex Particles

Wei, C., Plucinski, A., Nuasaen, S., Tripathi, A., Tangboriboonrat, P., & Tauer, K. (2017). Swelling-Induced Deformation of Spherical Latex Particles. Macromolecules, 50(1), 349-363. doi:10.1021/acs.macromol.6b02379.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-3337-4 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-4F5E-9
Genre: Journal Article
Alternative Title : Macromolecules

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2378287.pdf (Publisher version), 3MB
 
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 Creators:
Wei, Chunxiang1, Author              
Plucinski, Alexander1, Author
Nuasaen, Sukanya1, Author
Tripathi, Amit1, Author              
Tangboriboonrat, Pramuan, Author
Tauer, Klaus1, Author              
Affiliations:
1Klaus Tauer, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863320              

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 Abstract: Experimental evidence is presented showing that the direct formation of anisotropic colloidal polymer particles via aqueous heterophase polymerization is essentially controlled by the entropy gain of the linear fraction in the semi-interpenetrating network of the seed particles during swelling. Anisotropic particles are produced via photoinitiated polymerization, allowing swelling and polymerization to take place at the same temperature. These experiments prove that the temperature effect on rubber elasticity is, if at all, only of minor importance for the formation of anisotropic polymer particles. The major significance of swelling of the seed particles for the whole process is underlined by additional studies with optical microscopy and model simulations.

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 Dates: 2016-12-292017
 Publication Status: Published in print
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 Identifiers: DOI: 10.1021/acs.macromol.6b02379
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Title: Macromolecules
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: - Volume / Issue: 50 (1) Sequence Number: - Start / End Page: 349 - 363 Identifier: ISSN: 0024-9297